外消旋型 BINAP。用于不对称氢化催化,羰基还原等。钯催化芳基胺偶联反应的配体,用于制备去甲基硫代秋水?仙碱。可与 Cu(II) 联合使用催化芳基磺酰胺加成反应生成苯乙烯和烯烃。亦可用于钯催化的三联吡啶胺化反应。 Racemic version of BINAP Ligand employed in a palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines. Used with Cu (II) to catalyze addition of arylsulfonamides to styrenes and olefins. Amination of terpyridines with Pd catalysis.
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2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Dangerous GoodsCAS number:98327-87-8 molecular formula:C44H32P2
overview
compound introduction
Specs
| Chinese alias | 联萘二苯磷 | (±)-BINAP | ||
| English alias | 2,2'-bis(diphenylphosphino)-1,1'-binaphtyl | FT-0604001 | HY-Y0982 | MUALRAIOVNYAIW-UHFFFAOYSA- | OL10216 | Phosphine, 1,1'-(1,1'-binaphthalene)-2,2'-diylbis(1,1-diphenyl- | (R)-2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthalene | (S)-(-)-2,2'-Bis(diphenylph | ||
| CAS number | 98327-87-8 | molecular formula | C44H32P2 |
| molecular weight | 622.67 g/mol | Exact mass | ≥98% |
| PSA | 0.000 Ų | logp | 11.400 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H413: 可能对水生生物造成长期的有害影响
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304
WGK Germany:
3
Personal protective equipment:
Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
98327-87-8 | rac-BINAP.pdf





