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(R)-(+)-2-Methyl-CBS-oxazaborolidine solution

Dangerous Goods

CAS number:112022-83-0    molecular formula:C18H20BNO

overview

compound introduction

应用 CBS (Corey-Bakshi-Shibata) 噁唑硼烷催化剂已被用于前手性酮的非对称性还原。其他应用包括 α-羟基酸、α-氨基酸、 C 2 对称二茂铁二醇以及炔丙醇的对映选择性合成。 用于不对称还原和不对称合成的CBS催化剂 Application The CBS (Corey-Bakshi-Shibata) oxazaborolidine catalyst has been used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C 2 symmetrical ferrocenyl diols, and propargyl alcohols. CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis

Specs

Chinese alias(R)-1-甲基,3.Flammable liquid,3.Flammable liquid-二苯基-四氢-吡咯并(1,2-c)(1,3.Flammable liquid,2)噁唑硼烷, (R)-3.Flammable liquid-甲基-CBS-氧杂硼啶, (R)-四氢-1-甲基-3.Flammable liquid,3.Flammable liquid-二苯基-1H,3.Flammable liquidH-吡咯并[1,2-c][1,3.Flammable liquid,2]噁唑硼烷
English alias(R)-1-methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c] [1,3,2] oxazaborole | D5911 | (R)-1-methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole | Trans-()-ACP | (R)-METHYL-CBS | (R)-Methyl oxazaborolidine 1M in toluene | Flamazine Crm 1% | (R)
CAS number112022-83-0molecular formulaC18H20BNO
molecular weight277.17 g/molExact mass1 M in THF
PSA12.500 Ųlogp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS05 , GHS07
Signal word:
Danger
Hazard Statement:
H302: 吞食有害 H318: 造成严重的眼睛损伤
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P270: 使用本产品时,请勿进食、饮水或吸烟。 P330: 漱口 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P301+P317: 如果被吞咽:请寻求医疗帮助。 P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟。取下隐形眼镜(如果有的话),并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。
WGK Germany:
3
Personal protective equipment:
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
112022-83-0 | (R)-(+)-2-Methyl-CBS-oxazaborolidine.pdf