用于叔丁氧基羰基内酯和内酰胺化合物的钯催化对映选择性氟化。还可用于丁基锂作用下的二卤吡啶类化合物的亲电二氟化,以及用于三苯基膦作用下的醇直接转化成双苯磺酰亚胺类化合物。 稳定易处理的结晶物质,易于将 F+ 转化成烯醇化物和负碳离子。 Reagent employed in a palladium-catalyzed enantioselective fluorination of t-butoxycarbonyl lactones and lactams.Also used in the electrophilic difluorination of dihalopyridines with butyl lithium and in the direct conversion of alcohols to dibenzenesulfonamides with triphenylphosphine. Stable, easy-to-handle, crystalline material which readily transfers F+ to enolates and carbanions.
All
Chemical Reagents
Biomedicine
Organic raw materials
Inorganic chemical industry
intermediate
Agricultural chemicals
Auxiliaries and catalysts
Fragrances and Flavors
Dyes and Pigments
Daily chemical industry
N-Fluorobenzenesulfonimide
Dangerous GoodsCAS number:133745-75-2 molecular formula:(C6H5SO2)2NF
overview
compound introduction
Specs
| Chinese alias | N-氟二苯磺酰胺 | ||
| English alias | NFBS | NFSI | AN-584/43417535 | EN300-56237 | N-fluoranyl-N-(phenylsulfonyl)benzenesulfonamide | Q27110220 | AKOS005254552 | SY001955 | N-fluoro-di(benzenesulfonyl)-amine | N-fluorodi(benzenesulfonyl)-amine | A843443 | AC-1252 | DTXSID10343177 | UNII-38TG | ||
| CAS number | 133745-75-2 | molecular formula | (C6H5SO2)2NF |
| molecular weight | 315.34 g/mol | Exact mass | ≥97% |
| PSA | 88.300 Ų | logp | 2.600 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入:将人转移
WGK Germany:
3
Personal protective equipment:
dust mask type N95 (US), Eyeshields, Gloves
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
133745-75-2 | N-Fluorobenzenesulfonimide.pdf





