Provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters(1), cyclic β-(acylamino)acrylates(2) and a-phthalimide ketones
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(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin
Dangerous GoodsCAS number:486429-99-6 molecular formula:C39H32O2P2
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine | (R)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine | (S)-C3-TunePhos | E76416 | 1,13-bis(diphenylphosphino)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin | ( | ||
| CAS number | 486429-99-6 | molecular formula | C39H32O2P2 |
| molecular weight | 594.62 g/mol | Exact mass | ≥95% |
| PSA | 18.500 Ų | logp | 9 |
numbering system
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physicochemical properties
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Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入:将人转移
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