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Barium tert-butoxide

Dangerous Goods

CAS number:24363-36-8    molecular formula:

overview

compound introduction

Description Bariumtert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.Bariumtert-butoxide can be used:As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.To prepare yttrium and copper metal complexes by reacting with Y(thd)3and Cu(thd)2, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.In the iridium catalyzed allylic alkylation of non-stabilized enolates. Description Bariumtert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.Bariumtert-butoxide can be used:As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.To prepare yttrium and copper metal complexes by reacting with Y(thd)3and Cu(thd)2, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.In the iridium catalyzed allylic alkylation of non-stabilized enolates.

Specs

Chinese alias-
English aliasBarium di-t-butoxide
CAS number24363-36-8molecular formula
molecular weight283.55 g/molExact mass≥85%
PSA-logp-

numbering system

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physicochemical properties

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Safety information

Signal word:
Danger
Hazard Statement:
H335: 可能引起呼吸道刺激 H314: 造成严重的皮肤灼伤和眼睛损伤 H228: 易燃固体
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。 P310: 立即致电解毒中心或医生。
WGK Germany:
3

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MSDS

Found 1 shareMSDS
24363-36-8 | Barium tert-butoxide.pdf