[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium-based catalyst used for regioselective hydrogenation and enantioselective reductive amination reactions. Application: [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I)tetrafluoroborate can be used as a catalyst for the: Regioselective hydrogenation of thebaine to synthesize tetrahydrothebaine. Enantioselective reductive amination of α-ketoacids with benzylamines to synthesize α-N-benzylamino acids. Stereoselective hydrogenation of α-(hydroxymethyl)-acrylate derivatives to synthesize 3-hydroxy-2-methylpropanoates.
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[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate(contains CH2Cl2)
Dangerous GoodsCAS number:79255-71-3 molecular formula:C36H40BF4P2Rh
overview
compound introduction
Specs
| Chinese alias | [Rh(dppb)(COD)]BF4 | ||
| English alias | [Rh(dppb)(COD)]BF4 | ||
| CAS number | 79255-71-3 | molecular formula | C36H40BF4P2Rh |
| molecular weight | 724.36 g/mol | Exact mass | ≥98% |
| PSA | 0.000 Ų | logp | - |
numbering system
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physicochemical properties
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Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害 H312: 皮肤接触有害 H332: 吸入有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水
WGK Germany:
3
Production methods and uses
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downstream information
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MSDS
Found 1 shareMSDS
79255-71-3 | [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate.pdf





