Application The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions. Product class M-C, Homogeneous Catalysts, Hazari Catalyst, Indenyl Ligands Reaction type Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Suzuki-Miyaura Coupling Reaction Chemical properties Chemical formula C 26 H 30 Cl 2 Pd 2 Empirical formula [Pd(1- t Bu-Ind)Cl] 2 Molecular weight 626.27 Metal Pd Theoretical metal content 34 Metal purity 99.95 Applications & references Suzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]2 and IPr and an in situ generated solution of our Pd-cat. and IPr. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(tBu)3. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands. Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)
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Chloro(1-t-butylindenyl)palladium(II) dimer
Dangerous GoodsCAS number：1779569-01-5 molecular formula：C26H30Cl2Pd2
overview
compound introduction
Specs
| Chinese alias | Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200 | ||
| English alias | Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200 | ||
| CAS number | 1779569-01-5 | molecular formula | C26H30Cl2Pd2 |
| molecular weight | 626.26 g/mol | Exact mass | ≥99.95% metals basis |
| PSA | - | logp | - |
numbering system
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physicochemical properties
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Safety information
Signal word：
Warning
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激
Statement of Preventive Measures：
P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P264: 处理后要彻底洗手。 P337+P313: 如仍觉眼刺激：求医/就诊。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P332+P313: 如发生皮肤刺激：求医/就诊。
WGK Germany：
3
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MSDS
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1779569-01-5 | CX200, Umicore.pdf
