应用 溶于绿色溶剂2-甲基四氢呋喃 (2-MeTHF) 中的氯化铁（III）可用于： 作为酚醛偶联反应的温和氧化剂 用于芳基锂和酮烯醇化物的二聚体化 作为一种温和的路易斯酸催化剂催化烯反应 Nazarov环化、迈克尔加成和丙酮化反应 2-甲基四氢呋喃（2-MeTHF）： 一种生物质衍生的溶剂，广泛应用于有机化学 储存注意事项： 定期/蒸馏前检测过氧化物的生成。 General Description We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl 3 is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information. Application Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used: As a mild oxidant for phenolic coupling reaction. In dimerizing aryllithiumsand ketone enolates. As a mild Lewis acid catalyst to catalyzes ene reactions. In Nazarov cyclizations, Michael additions, and acetonation reactions. 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
All
Chemical Reagents
Biomedicine
Organic raw materials
Inorganic chemical industry
intermediate
Agricultural chemicals
Auxiliaries and catalysts
Fragrances and Flavors
Dyes and Pigments
Daily chemical industry
Iron(III) chloride solution
Dangerous GoodsCAS number：7705-08-0(2-MeTHF) molecular formula：FeCl3
overview
compound introduction
Specs
| Chinese alias | 氯化铁 溶液 | ||
| English alias | Chlorure perrique [French] | Fe/ppm Pd for nitro group reductions | NSC 51150 | trichloroiron | EN300-19478 | EPA Pesticide Chemical Code 034901 | Fe(III) chloride | FT-0627302 | Iron(III) chloride, CP | Natural molysite | UNII-U38V3ZVV3V | AKOS015902743 | ||
| CAS number | 7705-08-0(2-MeTHF) | molecular formula | FeCl3 |
| molecular weight | 162.2 g/mol | Exact mass | 0.2 M in 2-methyltet |
| PSA | 0.000 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS08 , GHS05 , GHS07 , GHS02
Signal word：
Danger
Hazard Statement：
H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤 H225: 高度易燃的液体和蒸气 H303: 要是吞了可能有害 H290: 可能腐蚀金属 H401: 对水生生物有毒 H371: 可能会损坏器官
Statement of Preventive Measures：
P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P403+P235: 存放在通风良好的地方。保持低温。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P303+P
WGK Germany：
3
Personal protective equipment：
Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
UN Number：
2924
General hazardous chemicals：
一般危化品
Packing Group：
II
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 0 shareMSDS
