Bis[(pinacolato)boryl]methane is an aryl boronate ester.Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity. Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction. Bis[(pinacolato)boryl]methane is an aryl boronate ester. Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity. Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction.
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Bis[(pinacolato)boryl]methane
Dangerous GoodsCAS number:78782-17-9 molecular formula:C13H26B2O4
overview
compound introduction
Specs
| Chinese alias | 二(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)甲烷 | ||
| English alias | AKOS027324523 | EN300-214736 | 1,3,2-Dioxaborolane, 2,2'-methylenebis[4,4,5,5-tetramethyl- | Bis[(pinacolato)boryl]methane | 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane | MFCD27977747 | FT-0663384 | 4,4, | ||
| CAS number | 78782-17-9 | molecular formula | C13H26B2O4 |
| molecular weight | 267.97 g/mol | Exact mass | ≥95%(GC) |
| PSA | 36.900 Ų | logp | - |
numbering system
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physicochemical properties
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Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入:将人转移
WGK Germany:
3
Production methods and uses
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MSDS
Found 1 shareMSDS
78782-17-9 | Bis[(pinacolato)boryl]methane.pdf





