Description (η5-Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.Catalyst mediates the transformation of alkynes to alcohols through ananti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol.
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(η⁵-Cyclopentadienyl)[N,N-dimethyl-Ν′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate
Dangerous GoodsCAS number:1603164-23-3 molecular formula:
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | Herzon Reductive Hydration Catalyst | ||
| CAS number | 1603164-23-3 | molecular formula | |
| molecular weight | 502.4 g/mol | Exact mass | - |
| PSA | - | logp | - |
numbering system
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physicochemical properties
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Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures:
P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P302+P352: 如皮肤沾染:用水充分清洗。
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MSDS
Found 1 shareMSDS
1603164-23-3 | (Cyclopentadienyl)[N,N-dimethyl-N'-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium(II) hexafluorophosphate.pdf




