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(2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

Dangerous Goods

CAS number:1445085-77-7    molecular formula:C43H56NO5PPdS

overview

compound introduction

Product Description :RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. Product Application :RuPhos Pd G3 can be used as a pre-catalyst in the following protocols: • Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles. • Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers. • Suzuki-Miyaura-cross-coupling of aminothiophenes.

Specs

Chinese aliasRuPhos-G3-环钯 | RuPhos-Pd-G3 | 甲磺酸(2-二环己基膦-2',6'-二异丙氧基-1,1'-联苯基)(2'-氨基-1,1'-联苯-2-基)钯(I | (2-二环己基膦基-2',6'-二异丙氧基-1,1'-联苯)[2-(2'-氨基-1,1'-联苯基)]钯(II)甲磺酸盐 | 甲磺酸(2-二环己基膦-2',6'-二异丙氧基-1,1'-联苯基)(2'-氨基-1,1'-联苯-2-基)钯(II)
English alias1445085-77-7 | Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) | RuPhos-Pd-G3 | MFCD22572684 | dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane;methanesulfonic acid;palladi
CAS number1445085-77-7molecular formulaC43H56NO5PPdS
molecular weight836.37 g/molExact mass≥98%
PSA107.000 Ųlogp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入:将人转移
WGK Germany:
3

Production methods and uses

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upstream information

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downstream information

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MSDS

Found 1 shareMSDS
1445085-77-7 | RuPhos Pd G3.pdf