聚合物键合的4-(二甲基氨基)吡啶是DMAP的聚合物键合当量。聚合物键合的4-(二甲氨基)吡啶已被用作酰化反应的催化剂。该化合物是2%交联的。 应用: 聚合物结合的4-(二甲氨基)吡啶在Michael加成和亚硝酸消除工艺步骤中用作负载碱,该步骤涉及在通用和基于方案的有效连续流动下使用β-硝基丙烯酸酯作为起始物料合成噻吩-2-羧酸酯。在固体非均相催化下,它还可以作为负载型催化剂,以环状2-硝基酮为起始原料制备ω-硝基酯。 4-(Dimethylamino)pyridine, polymer-bound is a polymer-bound equivalent of DMAP. 4-(Dimethylamino)pyridine, polymer-bound has been used as a catalyst for acylation reactions. The compound is 2% crosslinked.
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4-(Dimethylamino)pyridine, polymer-bound
Dangerous GoodsCAS number:82942-26-5 molecular formula:分子式:
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | 4-(N-benzyl-N-methyl-amino) pyridine | AKOS027557850 | SCHEMBL5182572 | DMAP on PS | polymer bound DMAP | ||
| CAS number | 82942-26-5 | molecular formula | 分子式: |
| molecular weight | 198.260 g/mol | Exact mass | extent of labeling: |
| PSA | 16.100 Ų | logp | 3.200 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入:将人转移
WGK Germany:
3
Personal protective equipment:
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
82942-26-5 | 4-(Dimethylamino)pyridine, polymer-bound.pdf





