Application Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 and supersilanol;
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Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆
Dangerous GoodsCAS number:2229858-27-7 molecular formula:C36H22F16IrN4P
overview
compound introduction
Specs
| Chinese alias | 4,4'-双(三氟甲基)-2,2'-联吡啶双[3,5-二氟-2-[5-甲基-2-吡啶基)苯基]铱(III)六氟磷酸盐 | 铱化合物Ir[dFMeppy]2-(4,4'-dCF3bpy)PF6 | ||
| English alias | 4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl]iridium(III)hexafluorophosphate | Photocatalyst | ||
| CAS number | 2229858-27-7 | molecular formula | C36H22F16IrN4P |
| molecular weight | 1037.75 g/mol | Exact mass | ≥95% |
| PSA | - | logp | - |
numbering system
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physicochemical properties
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Safety information
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P301+P312: 如误吞咽:如感觉不适,呼叫急救中心/医生。
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MSDS
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