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1-溴-2-硝基苯与一系列 β-卤代烯醛,-烯酮或 -酯发生钯[0]介导的 Ullmann 交叉偶联反应,得到相应的 β-芳基衍生物。研究报道了 1-溴-2-硝基苯与 β-溴-α,β-不饱和醛的钯[0]介导的 Ullmann 交叉偶联反应。1-溴-2-硝基苯可用于制备: · 4-甲氧基-2′-硝基二苯醚 · 1-甲氧基-3,5-二-(2-硝基-苯氧基)苯 · 5-羟基-3-甲氧基-2′-硝基二苯醚 1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported. 1-Bromo-2-nitrobenzene may be used in the preparation of: 4-methoxy-2′-nitrodiphenyl ether 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene 5-hydroxy-3-methoxy-2′-nitrodiphenyl ether
Chinese name
1-溴-2-硝基苯
English name
1-Bromo-2-nitrobenzene
Chinese alias
2-溴硝基苯
English alias
NSC403836 | NSC-403836 | B-8941 | CCRIS 3113 | AC-3283 | o-Nitrobromobenzene, liquid or solid [UN2732] [Keep away from food] | o-Nitrobromobenzene, liquid or solid | 1-Bromo-2-nitrobenzene 1000 microg/mL in Methanol | STL280234 | ghl.PD_Mitscher_leg0.917
CAS number
577-19-5
molecular formula
BrC6H4NO2
molecular weight
202.01 g/mol
Exact mass
≥99%
PSA
45.800 Ų
Logp
2.500
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Research chemical 1mL

Research chemical 1mL; supplied for laboratory research, analysis, inspection, and scientific procurement use; specifications: 1mL.

item number:91519B
Product model:1mL
level: 1mL
Lead Time:-
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