- Treatment： EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
- DOT label： 毒物
- Health hazard： ERG2024, 指南 153 (苯乙基溴): · 灭火或稀释水产生的径流可能具有腐蚀性和/或毒性，并造成环境污染。
- Hazard summary： 催泪剂；严重的皮肤、眼睛和粘膜刺激剂；与水分缓慢反应产生溴化氢；催泪剂；经食入、吸入和皮肤吸收有毒；[CAMEO] 造成烧伤和催泪；吸入可能对上呼吸道和肺部造成腐蚀性损伤；[Aldrich MSDS] 见α-氯代苯乙酮。
- reactive group： 酮类
- First aid measures： ERG2024, 指南 153 (苯乙基溴): 在加拿大，该产品可能需要制定紧急响应援助计划（ERAP）。请查阅运输文件和/或"ERAP"部分。
- exposure pathway： 口服(L626)；吸入(L626)；皮肤(L626)
- Harmful effect： 毒性肺炎 - 因吸入金属烟雾或有毒气体和蒸汽引起的肺部炎症。
- Toxicity summary： 苯乙基溴等有机溴化合物是强烷基化剂。因此，它们可以轻易修饰蛋白质表面的游离硫醇(半胱氨酸)和甲硫氨酸残基，导致酶、转运蛋白或膜功能紊乱。最可能的蛋白质靶标之一是TRPA1离子通道，该通道在眼睛、鼻子、嘴巴和肺的感觉神经(三叉神经)中表达。人肝醛脱氢酶同工酶E1和E2均可被苯乙基溴完全且不可逆地失活。这种靶向修饰可能导致肝毒性。
- Regulatory information： 新西兰化学品状态清单: 2-溴苯乙酮: 没有单独批准，但可在适当的团体标准下使用
- fire hazard： ERG2024, 指南 153 (苯乙基溴): · 物质可以熔融形式运输。
- fire fighting： FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. (ERG, 2024)
- Health Effects： 强催泪剂。吸入、摄入或皮肤接触该物质可能导致严重伤害或死亡。可能有肝毒性。它不是致癌物或致突变物。
- reactivity profile： 苯乙基溴与金属反应缓慢，引起轻微腐蚀。
- Symptoms and Signs： 苯乙基溴是强催泪剂。眼睛接触会引起刺激，特征为灼烧感、发红、流泪、炎症和可能的角膜损伤。引起皮肤刺激和可能的灼伤。可能引起胃肠道刺激，伴有恶心、呕吐和腹泻。引起呼吸道刺激。
- Isolation and evacuation： 疏散：ERG2024，指南153(苯乙基溴)：· 如果罐车、铁路罐车或公路罐车涉及火灾，应在所有方向上隔离800米(1/2英里)；同时，考虑在所有方向上初始疏散800米(1/2英里)。
- DOT ID and Guide： 2645 153
- Air and water reaction： 与空气中的水分缓慢反应形成溴化氢。
- Hazard categories and classifications： 特定靶器官毒性-单次接触 3级 (23.8%)
- Non-fire leakage response： 消除所有点火源(禁止吸烟、火焰、火花或明火)于立即区域。除非穿戴适当的防护服，否则不要触摸损坏的容器或泄漏物质。如果可以在不冒险的情况下，停止泄漏。防止进入水道、下水道、地下室或密闭区域。用干土、沙子或其他不可燃材料吸收或覆盖并转移到容器中。不要让水进入容器。(ERG, 2024)
- Personal protective equipment (PPE)： 佩戴正压自给式呼吸器（SCBA）。在没有火灾风险时，佩戴制造商特别推荐的化学防护服。结构消防员的防护服提供热保护，但仅提供有限的化学保护。（ERG，2024）
- Carcinogen Classification： 无致癌性迹象(未被IARC列出)。(L135)
- DOT Hazard Classification： Placard/Label(s)
- Accidental Release Measures： 泄漏: ERG2024, 指南 153 (苯乙基溴): · 切勿让水进入容器内。
- Emergency Response Planning Guidelines： 应急响应: ERG2024, 指南 153 (苯乙基溴): · 始终远离与火焰直接接触的储罐。
- Exposure Control and Personal Protection： 防护装备：ERG2024，指南153(苯乙基溴)：· 结构性消防员防护服提供热防护，但仅提供有限的化学防护。
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2-bromoacetophenone >=99%, Yong Yu GCYan Sheng Hua 5g
2-bromoacetophenone >=99%, Yong Yu GCYan Sheng Hua 5g Macklin 70-11-1, complete specifications, for production, research, laboratory testing and inspection, digital one-stop procurement platform for scientific materials.
