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应用 (1,5-环辛二烯)(五甲基环戊二烯)氯化钌是用于形成碳-碳和碳-杂原子键的均相催化剂。它可用于：催化炔基硼酸酯、炔丙醇和末端炔烃的环化三聚反应(cyclotrimerization)以形成芳基硼酸酯，芳基硼酸酯可进行钯（II）催化的羰基化反应以形成高度取代的苯酞。催化降冰片烯和降冰片二烯与炔烃的C-C偶联以形成2 + 2环加成产物。与2-二苯基膦基乙胺-叔丁醇钾结合形成一种可催化手性非外消旋仲醇快速消旋的三元催化剂体系。合成具有磷基配体（如双膦胺）的新有机钌配合物催化有机二硫化物和烯烃的加成反应生成二甲基二硫醚（vic-dithioether）。 Product class M-C, Homogeneous Catalysts, Arene/Aryl Ligands, Diene/Dienyl Ligands Reaction type Cyclization, Cyclopropanation, Ring Opening Reaction Chemical properties Chemical formula C 1 8 H 2 7 ClRu Empirical formula Ru(cod)(C 5 Me 5 )Cl Molecular weight 379.93 Metal Ru Theoretical metal content 27 Physical state crystalline Color Metal purity brown orange 99.95

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Chinese name

氯(五甲基环戊二烯)(环辛二烯)钌(II)

English name

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium

Chinese alias

Ru(cod)(C5Me5)Cl;Chloro(1,5-cyclooctadiene)pentamethylcyclopentadienylruthenium(II);1，5-Cyclooctadiene， ruthenium complex，Chloro(1，5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium，Chloro(1，5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium，

English alias

CAS number

92390-26-6

molecular formula

C18H27ClRu

molecular weight

379.93 g/mol

Exact mass

≥99.95% metals basis

PSA

Logp

Technical Documents

92390-26-6 | Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II).pdf
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