铑（I）的前体，在各种反应中用作前段催化剂，包括芳基和乙烯基-C-H键活化,环化异构体聚合和C-C键活化 应用： 双环辛烯氯化铑(I)二聚体可用作以下反应的催化剂： 通过芳基硼酸与α,β-不饱和磺酰基化合物的不对称1,4-加成，合成富对映体的偕二芳基磺酸盐。 N脱保护吲哚和吡咯的直接C-芳基化。 通过C-H键活化的在芳烃羧化反应。 Precusor for rhodium(I) and used as a precatalyst in a variety of reactions including aryl- and vinyl-C-H bond activation, hydroiminoacylation, cycloisomerization, and C-C bond activation Application： Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst: To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds. In direct C-arylation of N-unprotected indoles and pyrroles. In the carboxylation of arenes via C-H bond activation.