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外消旋型 BINAP。用于不对称氢化催化，羰基还原等。钯催化芳基胺偶联反应的配体，用于制备去甲基硫代秋水?仙碱。可与 Cu(II) 联合使用催化芳基磺酰胺加成反应生成苯乙烯和烯烃。亦可用于钯催化的三联吡啶胺化反应。 Racemic version of BINAP Ligand employed in a palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines. Used with Cu (II) to catalyze addition of arylsulfonamides to styrenes and olefins. Amination of terpyridines with Pd catalysis.

Specs ⸢ View details ⸥

Chinese name

(±)-2,2'-双-(二苯膦基)-1,1'-联萘

English name

2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene

Chinese alias

联萘二苯磷 | (±)-BINAP

English alias

CAS number

98327-87-8

molecular formula

C44H32P2

molecular weight

622.67 g/mol

Exact mass

≥98%

PSA

0.000 Å²

Logp

11.400

Technical Documents

98327-87-8 | rac-BINAP.pdf
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