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Application Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities.

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Chinese name

(1,1'-联萘)-2,2'-二胺

English name

1,1′-Binaphthyl-2,2′-diamine

Chinese alias

( )-1,1'-双(2-萘胺) | 1,1'-联萘-2,2'-二胺 | 2,2'-二氨基-1,1'-联萘

English alias

CAS number

4488-22-6

molecular formula

C20H16N2

molecular weight

284.35 g/mol

Exact mass

≥97%

PSA

52.000 Å²

Logp

4.700

Technical Documents

4488-22-6 | 1,1′-Binaphthyl-2,2′-diamine.pdf
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