Application The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions. Product class M-C, Homogeneous Catalysts, Hazari Catalyst, Indenyl Ligands Reaction type Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Suzuki-Miyaura Coupling Reaction Chemical properties Chemical formula C 26 H 30 Cl 2 Pd 2 Empirical formula [Pd(1- t Bu-Ind)Cl] 2 Molecular weight 626.27 Metal Pd Theoretical metal content 34 Metal purity 99.95 Applications & references Suzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]2 and IPr and an in situ generated solution of our Pd-cat. and IPr. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(tBu)3. Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878) Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands. Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)