溶于氯仿、二氯甲烷，水中分解。对空气和潮湿敏感。 应用 用于不对称和交叉偶联催化的预催化剂 Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane. Allylpalladium(II) chloride dimer has been employed for the following studies: ● Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation. ● Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides. ● Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines. ● As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M. Application Precatalysts for Asymmetric and Cross-Coupling Catalysis Product class M-C, Homogeneous Catalysts, Allyl Ligands Reaction type Cross Coupling Reactions with Arenes, Amination, Allylic Alkylation, Buchwald-Hartwig Aminaton, Asymmetric Reactions, CH-Activation, Mizoroki Heck Coupling Reaction Chemical properties Chemical formula C 6 H 1 0 Cl 2 Pd 2 Empirical formula [Pd(allyl)Cl] 2 Molecular weight 365.89 Metal Pd Theoretical metal content 58 Physical state crystalline Color yellow Metal purity 99.95